When I think of cartoon soundtrack music, 2 shows instantly come to mind: JONNY QUEST (1964-65) and SPIDER-MAN (1967-70).
Hoyt Curtin did all the music for JQ, and had been the guy for most Hanna-Barbera shows back then. His stuff really hit a high bar few have ever approached.
When SPIDER-MAN started from Grantray-Lawrence, they got a pair of big band composers involved. Bob Harris did the theme song, while Ray Ellis did all the background music (some of which was based on Harris' theme). This arrangement, funny enough, paralled that of the JAMES BOND movies (Monty Norman did the theme, John Barry did the scores) and the BATMAN tv series (Neil Hefti did the theme, Nelson Riddle did the scores).
However, when GL suddenly went BANKRUPT after only finishing the 1st episode of season 2, and Ralph Bakshi was hired to set up a new studio to do more episodes ON THE CHEAP, he resorted to using "Library Tracks" for the mountain of NEW music used in seasons 2-3, which was heard side-by-side with reused Ray Ellis music.
I found out about this in 2002, and was invited to join a Yahoo group dedicated to it in late 2004. I became so enraptured by music from the KPM, Capitol & DeWolf "libraries" that I collected and put together dozens of CDs of all this "stock" music, and even assembled a few "custom" soundtracks of my own, for stories I'd written myself.
I've often thought since then, if I were ever in a position to direct a movie, I'd PREFER using pre-existing music, since that way I'd know EXACTLY what I was getting in advance. I haven't really heard a memorable new instrumental movie score (or TV score) since the late 1980s!